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What is Thermodynamics in Chemistry?

Chemical dynamics is an important topic in chemistry class. It seeks to understand the relationship between heat and chemical reactions. The course involves study of enthalpy, internal energy, entropy and Gibbs free energy. Students studying thermodynamics grab important information about laws of thermodynamics and systems. For instance, a refrigerator or a car engine heavily rely on principles of thermodynamics.

Basically, thermodynamics and chemical reactions happen almost everywhere. For instance, you must have noticed that it is hotter upstairs than downstairs at home. A thermos flask is able to keep your drinks warm all day, that is thermodynamics at work! You see, that is how much we rely on thermodynamics in our daily life. That is why you need to get good grades in your thermodynamics class.

Chemical thermodynamics studies how heat works with relations to change in state and in chemical reaction. To explain the behavior, some rules and laws have been developed. The rules and laws explain the process and what is likely to happen spontaneously and which one require some help. Chemistry class requires students to memorize various principles. First, they need to understand something called systems.

Systems in Thermodynamics Chemistry Class

Systems are defined as series of components that are connected to work together. In chemical thermodynamics there are several types of systems. For in instance, a thermos flask has several components that have to work together to keep your coffee hot. The flask system comprises of components such as walls. Systems in thermodynamics include:

Isolated system

An isolated system in chemical thermodynamics is the one that does not allow transfer of mass or energy. Isolated system in aerodynamics has rigid walls. All the walls are heavily insulated. An example of an isolated thermodynamic system is the thermos flask. The flask keeps drinks hot or cold by preventing energy transfer. It does not allow exchange of energy or matter with the surrounding.

Closed system

A closed system in thermodynamics allows energy to pass in and out of the system. However, it does not allow mass to escape or enter into the system. A good example of closed system is pressure cooker on a stove. The pressure cooker allows mass to enter or leave it, but heat can pass into it.

Open Thermodynamic System

An open thermodynamic system on the other hand allows energy and matter to enter or leave the system. However, it doesn’t allow passing of matter in and out of the system. An example of an open thermodynamic system is when heating water without a lid. The heat escapes to the air in form of steam.

Laws of Thermodynamics

Laws of thermodynamics are the cornerstone of the chemical thermodynamics class. If you are looking for someone to help you with laws of thermodynamics look no further. The concept here is to understand change in internal energy. Students must understand what the first, second, and third law of dynamics. They can also seek help from chemical thermodynamic experts. Laws of thermodynamics are expressed in four fundamental principal laws.

The First law of Thermodynamics

The first law of thermodynamic states that heat is a form of energy. It also states that the thermodynamic process is subject to the conversion of energy. The first law of thermodynamics mean that energy cannot be created or destroyed. However, the energy can be transferred from one location to the other, or convert from one form of energy to another.

The first law of dynamics states that the internal energy must be equal to the work being done on the system. The energy can be plus or minus the heat that flows in and out of the system. Thus, it is the restatement of energy conversion. The first law can be expressed in form of an equation: ΔU = Q – W, where ΔU represents the change in internal energy, W is the work done by the system while Q represents heat added to the system.

The Second Law of Thermodynamics

The second law of thermodynamics explains the relationship between heat or thermo energy and other forms of energy with how it affects matter. The second law of thermodynamics only emphasizes on the quality of energy. It states that as energy is transformation and transfer, the more it is wasted. The law recognizes the presence of natural tendencies of isolated systems to degenerate into disordered state. It also states that you cannot create or destroy energy. Second law simply states that a natural process is that system progress increases disorder or entropy of the system. Second law principle states that thermodynamic processes involve conversion or transfer of heat energy. Additionally, the transfer is irreversible since it increases entropy.

Third Law of Thermodynamics

The third law of thermodynamics states that the entropy of a system approaches a constant value as its temperature approaches absolute zero. The constant value depends on parameters such as applied magnetic field or pressure. The absolute zero should be in a state with minimum possible energy. The law states that when the entropy is at ground state with minimum energy, the entropy will be at absolute zero.

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